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Subject Areas on Research
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A convenient synthesis of cis and trans 4-tert-butoxycarbonyl-substituted cyclohexylglycine.
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A new strategy toward indole alkaloids involving an intramolecular cycloaddition/rearrangement cascade.
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A robust platform for the synthesis of new tetracycline antibiotics.
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An efficient synthesis of fluorinated azaheterocycles by aminocyclization of alkenes.
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Application of ruthenium-induced macrocyclization for the construction of macrocyclic depsipeptides.
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Bicyclo[3.2.0]heptane mechanophores for the non-scissile and photochemically reversible generation of reactive bis-enones.
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Close the ring to break the cycle: tandem quinolone-alkyne-cyclisation gives access to tricyclic pyrrolo[1,2-a]quinolin-5-ones with potent anti-protozoal activity.
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Cyclization/hydrosilylation of functionalized 1,6-diynes catalyzed by cationic platinum complexes containing bidentate nitrogen ligands.
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Dichloroketene-induced cyclizations of vinyl sulfilimines: application of the method in the synthesis of (+/-)-desoxyeseroline.
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Enantioselective cyclization/hydrosilylation of 1,6-enynes catalyzed by a cationic rhodium bis(phosphine) complex.
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Enantioselective synthesis of cyclic enol ethers and all-carbon quaternary stereogenic centers through catalytic asymmetric ring-closing metathesis.
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Expanding the synthetic method and structural diversity potential for the intramolecular Aza Diels-Alder cyclization.
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Gold(I)-catalyzed enantioselective intramolecular dehydrative amination of allylic alcohols with carbamates.
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Gold(I)-catalyzed intramolecular amination of allylic alcohols with alkylamines.
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Gold(I)-catalyzed intramolecular dihydroamination of allenes with N,N'-disubstituted ureas to form bicyclic imidazolidin-2-ones.
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Mechanism of palladium-catalyzed diene cyclization/hydrosilylation: direct observation of intramolecular carbometalation.
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Metabolomics and mass isotopomer analysis as a strategy for pathway discovery: pyrrolyl and cyclopentenyl derivatives of the pro-drug of abuse, levulinate.
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Metal-catalyzed nitrogen-atom transfer methods for the oxidation of aliphatic C-H bonds.
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Model Studies To Access the [6,7,5,5]-Core of Ineleganolide Using Tandem Translactonization-Cope or Cyclopropanation-Cope Rearrangements as Key Steps.
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One-pot synthesis of 3-azido- and 3-aminopiperidines by intramolecular cyclization of unsaturated amines.
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Palladium-catalyzed asymmetric diene cyclization/hydrosilylation employing functionalized silanes and disiloxanes.
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Platinum-catalyzed intramolecular alkylation of indoles with unactivated olefins.
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Platinum-catalyzed intramolecular hydroalkoxylation of gamma- and delta-hydroxy olefins to form cyclic ethers.
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Post-assembly derivatization of electrospun nanofibers via strain-promoted azide alkyne cycloaddition.
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Recent developments in enantioselective gold(I) catalysis.
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Stereoselective synthesis of tetrahydrofuran lignans via BF(3) x OEt(2)-promoted reductive deoxygenation/epimerization of cyclic hemiketal: synthesis of (-)-odoratisol C, (-)-futokadsurin A, (-)-veraguensin, (+)-fragransin A(2), (+)-galbelgin, and (+)-talaumidin.
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Stress-responsive polymers containing cyclobutane core mechanophores: reactivity and mechanistic insights.
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Synthesis of the tetracyclic framework of the erythrina alkaloids using a [4 + 2]-cycloaddition/Rh(I)-catalyzed cascade of 2-imidofurans.
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Synthetic and mechanistic studies of the cycloisomerization and cyclization/hydrosilylation of functionalized dienes catalyzed by cationic palladium(II) complexes.
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Total synthesis and molecular target of largazole, a histone deacetylase inhibitor.
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Unified Enantioselective, Convergent Synthetic Approach toward the Furanobutenolide-Derived Polycyclic Norcembranoid Diterpenes: Synthesis of a Series of Ineleganoloids by Oxidation-State Manipulation of the Carbocyclic Core.
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Use of pentamethyldisiloxane in the palladium-catalyzed cyclization/hydrosilylation of functionalized dienes.
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Keywords of People