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Experimental evaluation of the electron donor ability of a gold phosphine fragment in a gold carbene complex.

Publication ,  Journal Article
Brooner, REM; Widenhoefer, RA
Published in: Chemical communications (Cambridge, England)
March 2014

X-ray analysis of the gold cyclopropyl(methoxy)carbene complex [(P)AuC(OMe)(c-Pr)](+) SbF6(-) [P = P(t-Bu)2o-biphenyl] and comparison to extant protonated cyclopropyl ketones indicates that electron donation from the (P)Au fragment to the electron-deficient C1 atom is similar to that provided by a cyclopropyl group.

Duke Scholars

Published In

Chemical communications (Cambridge, England)

DOI

EISSN

1364-548X

ISSN

1359-7345

Publication Date

March 2014

Volume

50

Issue

19

Start / End Page

2420 / 2423

Related Subject Headings

  • Organic Chemistry
  • 40 Engineering
  • 34 Chemical sciences
  • 03 Chemical Sciences
 

Citation

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Brooner, R. E. M., & Widenhoefer, R. A. (2014). Experimental evaluation of the electron donor ability of a gold phosphine fragment in a gold carbene complex. Chemical Communications (Cambridge, England), 50(19), 2420–2423. https://doi.org/10.1039/c3cc48869a
Brooner, Rachel E. M., and Ross A. Widenhoefer. “Experimental evaluation of the electron donor ability of a gold phosphine fragment in a gold carbene complex.Chemical Communications (Cambridge, England) 50, no. 19 (March 2014): 2420–23. https://doi.org/10.1039/c3cc48869a.
Brooner REM, Widenhoefer RA. Experimental evaluation of the electron donor ability of a gold phosphine fragment in a gold carbene complex. Chemical communications (Cambridge, England). 2014 Mar;50(19):2420–3.
Brooner, Rachel E. M., and Ross A. Widenhoefer. “Experimental evaluation of the electron donor ability of a gold phosphine fragment in a gold carbene complex.Chemical Communications (Cambridge, England), vol. 50, no. 19, Mar. 2014, pp. 2420–23. Epmc, doi:10.1039/c3cc48869a.
Brooner REM, Widenhoefer RA. Experimental evaluation of the electron donor ability of a gold phosphine fragment in a gold carbene complex. Chemical communications (Cambridge, England). 2014 Mar;50(19):2420–2423.
Journal cover image

Published In

Chemical communications (Cambridge, England)

DOI

EISSN

1364-548X

ISSN

1359-7345

Publication Date

March 2014

Volume

50

Issue

19

Start / End Page

2420 / 2423

Related Subject Headings

  • Organic Chemistry
  • 40 Engineering
  • 34 Chemical sciences
  • 03 Chemical Sciences