Skip to main content
Journal cover image

[(CH3)3NCH2CH2NH3]SnI4: a layered perovskite with quaternary/primary ammonium dications and short interlayer iodine-iodine contacts.

Publication ,  Journal Article
Xu, Z; Mitzi, DB; Medeiros, DR
Published in: Inorganic chemistry
March 2003

The organic-inorganic hybrid [(CH(3))(3)NCH(2)CH(2)NH(3)]SnI(4) presents a layered perovskite structure, templated by an organic dication containing both a primary and a quaternary ammonium group. Due to the high charge density and small size of the organic cation, the separation of the perovskite layers is small and short iodine-iodine contacts of 4.19 A are formed between the layers. Optical thin-film measurements on this compound indicate a significant red shift of the exciton peak (630 nm) associated with the band gap, as compared with other SnI(4)(2)(-)-based layered perovskite structures.

Duke Scholars

Published In

Inorganic chemistry

DOI

EISSN

1520-510X

ISSN

0020-1669

Publication Date

March 2003

Volume

42

Issue

5

Start / End Page

1400 / 1402

Related Subject Headings

  • Inorganic & Nuclear Chemistry
  • 3403 Macromolecular and materials chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0306 Physical Chemistry (incl. Structural)
  • 0302 Inorganic Chemistry
 

Citation

APA
Chicago
ICMJE
MLA
NLM
Xu, Z., Mitzi, D. B., & Medeiros, D. R. (2003). [(CH3)3NCH2CH2NH3]SnI4: a layered perovskite with quaternary/primary ammonium dications and short interlayer iodine-iodine contacts. Inorganic Chemistry, 42(5), 1400–1402. https://doi.org/10.1021/ic0261981
Xu, Zhengtao, David B. Mitzi, and David R. Medeiros. “[(CH3)3NCH2CH2NH3]SnI4: a layered perovskite with quaternary/primary ammonium dications and short interlayer iodine-iodine contacts.Inorganic Chemistry 42, no. 5 (March 2003): 1400–1402. https://doi.org/10.1021/ic0261981.
Xu, Zhengtao, et al. “[(CH3)3NCH2CH2NH3]SnI4: a layered perovskite with quaternary/primary ammonium dications and short interlayer iodine-iodine contacts.Inorganic Chemistry, vol. 42, no. 5, Mar. 2003, pp. 1400–02. Epmc, doi:10.1021/ic0261981.
Journal cover image

Published In

Inorganic chemistry

DOI

EISSN

1520-510X

ISSN

0020-1669

Publication Date

March 2003

Volume

42

Issue

5

Start / End Page

1400 / 1402

Related Subject Headings

  • Inorganic & Nuclear Chemistry
  • 3403 Macromolecular and materials chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0306 Physical Chemistry (incl. Structural)
  • 0302 Inorganic Chemistry