[(CH3)3NCH2CH2NH3]SnI4: a layered perovskite with quaternary/primary ammonium dications and short interlayer iodine-iodine contacts.
Publication
, Journal Article
Xu, Z; Mitzi, DB; Medeiros, DR
Published in: Inorganic chemistry
March 2003
The organic-inorganic hybrid [(CH(3))(3)NCH(2)CH(2)NH(3)]SnI(4) presents a layered perovskite structure, templated by an organic dication containing both a primary and a quaternary ammonium group. Due to the high charge density and small size of the organic cation, the separation of the perovskite layers is small and short iodine-iodine contacts of 4.19 A are formed between the layers. Optical thin-film measurements on this compound indicate a significant red shift of the exciton peak (630 nm) associated with the band gap, as compared with other SnI(4)(2)(-)-based layered perovskite structures.
Duke Scholars
Published In
Inorganic chemistry
DOI
EISSN
1520-510X
ISSN
0020-1669
Publication Date
March 2003
Volume
42
Issue
5
Start / End Page
1400 / 1402
Related Subject Headings
- Inorganic & Nuclear Chemistry
- 3403 Macromolecular and materials chemistry
- 3402 Inorganic chemistry
- 0399 Other Chemical Sciences
- 0306 Physical Chemistry (incl. Structural)
- 0302 Inorganic Chemistry
Citation
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MLA
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Xu, Z., Mitzi, D. B., & Medeiros, D. R. (2003). [(CH3)3NCH2CH2NH3]SnI4: a layered perovskite with quaternary/primary ammonium dications and short interlayer iodine-iodine contacts. Inorganic Chemistry, 42(5), 1400–1402. https://doi.org/10.1021/ic0261981
Xu, Zhengtao, David B. Mitzi, and David R. Medeiros. “[(CH3)3NCH2CH2NH3]SnI4: a layered perovskite with quaternary/primary ammonium dications and short interlayer iodine-iodine contacts.” Inorganic Chemistry 42, no. 5 (March 2003): 1400–1402. https://doi.org/10.1021/ic0261981.
Xu Z, Mitzi DB, Medeiros DR. [(CH3)3NCH2CH2NH3]SnI4: a layered perovskite with quaternary/primary ammonium dications and short interlayer iodine-iodine contacts. Inorganic chemistry. 2003 Mar;42(5):1400–2.
Xu, Zhengtao, et al. “[(CH3)3NCH2CH2NH3]SnI4: a layered perovskite with quaternary/primary ammonium dications and short interlayer iodine-iodine contacts.” Inorganic Chemistry, vol. 42, no. 5, Mar. 2003, pp. 1400–02. Epmc, doi:10.1021/ic0261981.
Xu Z, Mitzi DB, Medeiros DR. [(CH3)3NCH2CH2NH3]SnI4: a layered perovskite with quaternary/primary ammonium dications and short interlayer iodine-iodine contacts. Inorganic chemistry. 2003 Mar;42(5):1400–1402.
Published In
Inorganic chemistry
DOI
EISSN
1520-510X
ISSN
0020-1669
Publication Date
March 2003
Volume
42
Issue
5
Start / End Page
1400 / 1402
Related Subject Headings
- Inorganic & Nuclear Chemistry
- 3403 Macromolecular and materials chemistry
- 3402 Inorganic chemistry
- 0399 Other Chemical Sciences
- 0306 Physical Chemistry (incl. Structural)
- 0302 Inorganic Chemistry