Synthesis, structure, and reactivity of a gold carbenoid complex that lacks heteroatom stabilization.

Published

Journal Article

Hydride abstraction from the neutral gold cycloheptatrienyl complex [(P)Au(η(1)-C7H7)] (P=P(tBu)2(o-biphenyl)) with triphenylcarbenium tetrafluoroborate at -80 °C led to the isolation of the cationic gold cycloheptatrienylidene complex [(P)Au(η(1)-C7H6)](+) BF4(-) in 52% yield, which was characterized in solution and by single-crystal X-ray diffraction. This cycloheptatrienylidene complex represents the first example of a gold carbenoid complex that lacks conjugated heteroatom stabilization of the electron-deficient C1 carbon atom. The cycloheptatrienylidene ligand of this complex is reactive; it can be reduced by mild hydride donors, and converted to tropone in the presence of pyridine N-oxide.

Full Text

Duke Authors

Cited Authors

  • Harris, RJ; Widenhoefer, RA

Published Date

  • August 2014

Published In

Volume / Issue

  • 53 / 35

Start / End Page

  • 9369 - 9371

PubMed ID

  • 24990811

Pubmed Central ID

  • 24990811

Electronic International Standard Serial Number (EISSN)

  • 1521-3773

International Standard Serial Number (ISSN)

  • 1433-7851

Digital Object Identifier (DOI)

  • 10.1002/anie.201404882

Language

  • eng