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Tetrakis[(9-oxo-10-thiaxanthen-2-yl-oxyethyl)ammonium] decaiodotri- plumbate(II)

Publication ,  Journal Article
Maxcy, KR; Willett, RD; Mitzi, DB; Afzali, A
Published in: Acta Crystallographica Section E: Structure Reports Online
June 1, 2003

The structure of the title compound, (AETO)4[Pb 3I10] or (C15H14NO 2S)4[Pb3I10], contains chains of octahedrally coordinated PbI6 species along with two crystallographically independent AETO cations that hydrogen bond to these chains. Individual (Pb3I10)n4n- chains are linked into layers via hydrogen bonds. The cations sheath each layer of chains, forming cation-chain-cation triple layers. Cations on adjacent triple layers interdigitate, forming stacks running parallel to [110]. There is a range of hydrogen bonding interactions between each cation and the (Pb 3I10)n4n- chains. © 2003 International Union of Crystallography Printed in Great Britain - all rights reserved.

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Published In

Acta Crystallographica Section E: Structure Reports Online

DOI

ISSN

1600-5368

Publication Date

June 1, 2003

Volume

59

Issue

6

Related Subject Headings

  • Inorganic & Nuclear Chemistry
  • 03 Chemical Sciences
 

Citation

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Maxcy, K. R., Willett, R. D., Mitzi, D. B., & Afzali, A. (2003). Tetrakis[(9-oxo-10-thiaxanthen-2-yl-oxyethyl)ammonium] decaiodotri- plumbate(II). Acta Crystallographica Section E: Structure Reports Online, 59(6). https://doi.org/10.1107/S1600536803007414
Maxcy, K. R., R. D. Willett, D. B. Mitzi, and A. Afzali. “Tetrakis[(9-oxo-10-thiaxanthen-2-yl-oxyethyl)ammonium] decaiodotri- plumbate(II).” Acta Crystallographica Section E: Structure Reports Online 59, no. 6 (June 1, 2003). https://doi.org/10.1107/S1600536803007414.
Maxcy KR, Willett RD, Mitzi DB, Afzali A. Tetrakis[(9-oxo-10-thiaxanthen-2-yl-oxyethyl)ammonium] decaiodotri- plumbate(II). Acta Crystallographica Section E: Structure Reports Online. 2003 Jun 1;59(6).
Maxcy, K. R., et al. “Tetrakis[(9-oxo-10-thiaxanthen-2-yl-oxyethyl)ammonium] decaiodotri- plumbate(II).” Acta Crystallographica Section E: Structure Reports Online, vol. 59, no. 6, June 2003. Scopus, doi:10.1107/S1600536803007414.
Maxcy KR, Willett RD, Mitzi DB, Afzali A. Tetrakis[(9-oxo-10-thiaxanthen-2-yl-oxyethyl)ammonium] decaiodotri- plumbate(II). Acta Crystallographica Section E: Structure Reports Online. 2003 Jun 1;59(6).
Journal cover image

Published In

Acta Crystallographica Section E: Structure Reports Online

DOI

ISSN

1600-5368

Publication Date

June 1, 2003

Volume

59

Issue

6

Related Subject Headings

  • Inorganic & Nuclear Chemistry
  • 03 Chemical Sciences