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Importance of a nanoscience approach in the understanding of major aqueous contamination scenarios: case study from a recent coal ash spill.

Publication ,  Journal Article
Yang, Y; Colman, BP; Bernhardt, ES; Hochella, MF
Published in: Environmental science & technology
March 2015

A coal ash spill that occurred from an ash impoundment pond into the Dan River, North Carolina, provided a unique opportunity to study the significance and role of naturally occurring and incidental nanomaterials associated with contaminant distribution from a large-scale, acute aquatic contamination event. Besides traditional measurements of bulk watercolumn and sediment metal concentrations, the nanoparticle (NP) analyses are based on cross-flow ultrafiltration (CFUF) and advanced transmission electron microscopy (TEM) techniques. A drain pipe fed by coal ash impoundment seepage showed a high level of arsenic, with concentrations many times over the EPA limit. The majority of the arsenic was found sorbed to large aggregates dominated by incidental iron oxyhydroxide (ferrihydrite) NPs, while the remainder of the arsenic was truly dissolved. These ferrihydrites were probably formed in situ where Fe(II) was leached through subsurface flowpaths into an aerobic environment, and further act as a significant contributor to the elevated As concentrations in downstream sediments after the spill. In addition, we discovered and describe a photocatalytic nano-TiO2 phase (anatase) present in the coal ash impacted river water that was also carrying/transporting transition metals (Cu, Fe), which may also have environmental consequences.

Duke Scholars

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Published In

Environmental science & technology

DOI

EISSN

1520-5851

ISSN

0013-936X

Publication Date

March 2015

Volume

49

Issue

6

Start / End Page

3375 / 3382

Related Subject Headings

  • Water Pollutants, Chemical
  • Ultrafiltration
  • Titanium
  • Rivers
  • North Carolina
  • Nanotechnology
  • Microscopy, Electron, Transmission
  • Metals
  • Metal Nanoparticles
  • Ferric Compounds
 

Citation

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Yang, Y., Colman, B. P., Bernhardt, E. S., & Hochella, M. F. (2015). Importance of a nanoscience approach in the understanding of major aqueous contamination scenarios: case study from a recent coal ash spill. Environmental Science & Technology, 49(6), 3375–3382. https://doi.org/10.1021/es505662q
Yang, Yi, Benjamin P. Colman, Emily S. Bernhardt, and Michael F. Hochella. “Importance of a nanoscience approach in the understanding of major aqueous contamination scenarios: case study from a recent coal ash spill.Environmental Science & Technology 49, no. 6 (March 2015): 3375–82. https://doi.org/10.1021/es505662q.
Yang Y, Colman BP, Bernhardt ES, Hochella MF. Importance of a nanoscience approach in the understanding of major aqueous contamination scenarios: case study from a recent coal ash spill. Environmental science & technology. 2015 Mar;49(6):3375–82.
Yang, Yi, et al. “Importance of a nanoscience approach in the understanding of major aqueous contamination scenarios: case study from a recent coal ash spill.Environmental Science & Technology, vol. 49, no. 6, Mar. 2015, pp. 3375–82. Epmc, doi:10.1021/es505662q.
Yang Y, Colman BP, Bernhardt ES, Hochella MF. Importance of a nanoscience approach in the understanding of major aqueous contamination scenarios: case study from a recent coal ash spill. Environmental science & technology. 2015 Mar;49(6):3375–3382.
Journal cover image

Published In

Environmental science & technology

DOI

EISSN

1520-5851

ISSN

0013-936X

Publication Date

March 2015

Volume

49

Issue

6

Start / End Page

3375 / 3382

Related Subject Headings

  • Water Pollutants, Chemical
  • Ultrafiltration
  • Titanium
  • Rivers
  • North Carolina
  • Nanotechnology
  • Microscopy, Electron, Transmission
  • Metals
  • Metal Nanoparticles
  • Ferric Compounds