Hyperpolarization of Nitrogen-15 Schiff Bases by Reversible Exchange Catalysis with para-Hydrogen.

Journal Article

NMR with thermal polarization requires relatively concentrated samples, particularly for nuclei with low abundance and low gyromagnetic ratios, such as (15) N. We expand the substrate scope of SABRE, a recently introduced hyperpolarization method, to allow access to (15) N-enriched Schiff bases. These substrates show fractional (15) N polarization levels of up to 2 % while having only minimal (1) H enhancements.

Full Text

Duke Authors

Cited Authors

  • Logan, AWJ; Theis, T; Colell, JFP; Warren, WS; Malcolmson, SJ

Published Date

  • July 2016

Published In

Volume / Issue

  • 22 / 31

Start / End Page

  • 10777 - 10781

PubMed ID

  • 27218241

Electronic International Standard Serial Number (EISSN)

  • 1521-3765

International Standard Serial Number (ISSN)

  • 0947-6539

Digital Object Identifier (DOI)

  • 10.1002/chem.201602393

Language

  • eng