Gold-Catalyzed Intermolecular, anti-Markovnikov Hydroarylation of Methylenecyclopropanes with Indoles.
Publication
, Journal Article
Timmerman, JC; Schmitt, WW; Widenhoefer, RA
Published in: Organic letters
October 2016
Cationic gold complexes containing an N-heterocyclic carbene ligand catalyze the intermolecular anti-Markovnikov hydroarylation of monosubstituted and cis- and trans-disubstituted methylenecyclopropanes (MCPs) with N-alkyl and 1,2-dialkyl indoles to form the corresponding 3-(cyclopropylmethyl)indoles in high regio- and diastereoselectivity and in good to excellent chemical yield.
Duke Scholars
Published In
Organic letters
DOI
EISSN
1523-7052
ISSN
1523-7060
Publication Date
October 2016
Volume
18
Issue
19
Start / End Page
4966 / 4969
Related Subject Headings
- Organic Chemistry
- 34 Chemical sciences
- 03 Chemical Sciences
Citation
APA
Chicago
ICMJE
MLA
NLM
Timmerman, J. C., Schmitt, W. W., & Widenhoefer, R. A. (2016). Gold-Catalyzed Intermolecular, anti-Markovnikov Hydroarylation of Methylenecyclopropanes with Indoles. Organic Letters, 18(19), 4966–4969. https://doi.org/10.1021/acs.orglett.6b02431
Timmerman, Jacob C., William W. Schmitt, and Ross A. Widenhoefer. “Gold-Catalyzed Intermolecular, anti-Markovnikov Hydroarylation of Methylenecyclopropanes with Indoles.” Organic Letters 18, no. 19 (October 2016): 4966–69. https://doi.org/10.1021/acs.orglett.6b02431.
Timmerman JC, Schmitt WW, Widenhoefer RA. Gold-Catalyzed Intermolecular, anti-Markovnikov Hydroarylation of Methylenecyclopropanes with Indoles. Organic letters. 2016 Oct;18(19):4966–9.
Timmerman, Jacob C., et al. “Gold-Catalyzed Intermolecular, anti-Markovnikov Hydroarylation of Methylenecyclopropanes with Indoles.” Organic Letters, vol. 18, no. 19, Oct. 2016, pp. 4966–69. Epmc, doi:10.1021/acs.orglett.6b02431.
Timmerman JC, Schmitt WW, Widenhoefer RA. Gold-Catalyzed Intermolecular, anti-Markovnikov Hydroarylation of Methylenecyclopropanes with Indoles. Organic letters. 2016 Oct;18(19):4966–4969.
Published In
Organic letters
DOI
EISSN
1523-7052
ISSN
1523-7060
Publication Date
October 2016
Volume
18
Issue
19
Start / End Page
4966 / 4969
Related Subject Headings
- Organic Chemistry
- 34 Chemical sciences
- 03 Chemical Sciences