Vibrational spectra of fluvalinate

Published

Journal Article

The normal Raman spectrum (NRS), Fourier transform infrared spectrum (FTIRS) and surface‐enhanced Raman spectrum (SERS) of the important insecticide and acaricide fluvalinate (C26H22ClF3N2O3) were recorded for the first time. The spectral data are discussed in terms of characteristic chemical group frequencies and bonds. The fingerprint regions of fluvalinate vibrations that are distinct in FTIRS are identified and presented with the different fingerprint frequencies that are only characteristic to NRS. The enhancement of the benzene ring‐breathing vibration of fluvalinate in SERS is a useful mode for trace analysis for residues of this pesticide at the subnanogram level. The vibrational spectra and polarization characteristics of NRS frequencies are useful as reference spectra for this pesticide in the qualitative analysis of its residues. Copyright © 1993 John Wiley & Sons, Ltd.

Full Text

Duke Authors

Cited Authors

  • Narayanan, VA; Begun, GM; Stump, NA; Stokes, DL; Vo‐Dinh, T

Published Date

  • January 1, 1993

Published In

Volume / Issue

  • 24 / 3

Start / End Page

  • 123 - 128

Electronic International Standard Serial Number (EISSN)

  • 1097-4555

International Standard Serial Number (ISSN)

  • 0377-0486

Digital Object Identifier (DOI)

  • 10.1002/jrs.1250240302

Citation Source

  • Scopus