Rovibronic Spectroscopy of Sympathetically Cooled 40CaH+
Publication
, Journal Article
Calvin, AT; Janardan, S; Condoluci, J; Rugango, R; Pretzsch, E; Shu, G; Brown, KR
Published in: The Journal of Physical Chemistry A
March 9, 2018
We measure the rovibronic transitions X 1Σ+, v″ = 0, J″ → A 1Σ+, v' = 0-3, J' of CaH+ and obtain rotational constants for the A 1Σ+ state. The spectrum is obtained using two-photon photodissociation of CaH+ cotrapped with Doppler cooled Ca+. The excitation is driven by a mode-locked, frequency-doubled Ti:Sapph laser, which is then pulse shaped to narrow the spectral bandwidth. The measured values of the rotational constants are in agreement with ab initio theory.
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Published In
The Journal of Physical Chemistry A
DOI
EISSN
1520-5215
ISSN
1089-5639
Publication Date
March 9, 2018
Volume
122
Issue
12
Start / End Page
3177 / 3181
Related Subject Headings
- 5102 Atomic, molecular and optical physics
- 3407 Theoretical and computational chemistry
- 3406 Physical chemistry
- 0307 Theoretical and Computational Chemistry
- 0306 Physical Chemistry (incl. Structural)
- 0202 Atomic, Molecular, Nuclear, Particle and Plasma Physics
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Calvin, A. T., Janardan, S., Condoluci, J., Rugango, R., Pretzsch, E., Shu, G., & Brown, K. R. (2018). Rovibronic Spectroscopy of Sympathetically Cooled 40CaH+. The Journal of Physical Chemistry A, 122(12), 3177–3181. https://doi.org/10.1021/acs.jpca.7b12823
Calvin, Aaron T., Smitha Janardan, John Condoluci, Réne Rugango, Eric Pretzsch, Gang Shu, and Kenneth R. Brown. “Rovibronic Spectroscopy of Sympathetically Cooled 40CaH+.” The Journal of Physical Chemistry A 122, no. 12 (March 9, 2018): 3177–81. https://doi.org/10.1021/acs.jpca.7b12823.
Calvin AT, Janardan S, Condoluci J, Rugango R, Pretzsch E, Shu G, et al. Rovibronic Spectroscopy of Sympathetically Cooled 40CaH+. The Journal of Physical Chemistry A. 2018 Mar 9;122(12):3177–81.
Calvin, Aaron T., et al. “Rovibronic Spectroscopy of Sympathetically Cooled 40CaH+.” The Journal of Physical Chemistry A, vol. 122, no. 12, Mar. 2018, pp. 3177–81. Manual, doi:10.1021/acs.jpca.7b12823.
Calvin AT, Janardan S, Condoluci J, Rugango R, Pretzsch E, Shu G, Brown KR. Rovibronic Spectroscopy of Sympathetically Cooled 40CaH+. The Journal of Physical Chemistry A. 2018 Mar 9;122(12):3177–3181.
Published In
The Journal of Physical Chemistry A
DOI
EISSN
1520-5215
ISSN
1089-5639
Publication Date
March 9, 2018
Volume
122
Issue
12
Start / End Page
3177 / 3181
Related Subject Headings
- 5102 Atomic, molecular and optical physics
- 3407 Theoretical and computational chemistry
- 3406 Physical chemistry
- 0307 Theoretical and Computational Chemistry
- 0306 Physical Chemistry (incl. Structural)
- 0202 Atomic, Molecular, Nuclear, Particle and Plasma Physics