Iron(MCP) Complexes Catalyze Aziridination with Olefins As Limiting Reagents.


Journal Article

Herein described are the first efficient nitrogen-atom transfer reactions mediated by iron N, N'-dimethyl- N, N'-bis(2-pyridinylmethyl)cyclohexane-1,2-diamine- (MCP-) and 2-({1-[(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl}methyl)pyridine-type (PDP-type) complexes. These catalysts affect styrene aziridination under mild conditions based on a limiting quantity of olefin substrate.

Full Text

Duke Authors

Cited Authors

  • Shehata, MF; Ayer, SK; Roizen, JL

Published Date

  • May 2018

Published In

Volume / Issue

  • 83 / 9

Start / End Page

  • 5072 - 5081

PubMed ID

  • 29648809

Pubmed Central ID

  • 29648809

Electronic International Standard Serial Number (EISSN)

  • 1520-6904

International Standard Serial Number (ISSN)

  • 0022-3263

Digital Object Identifier (DOI)

  • 10.1021/acs.joc.8b00402


  • eng