Network Modulus and Superelasticity

Journal Article (Academic article)

We discuss the elastic modulus G and swelling/deswelling behavior of networks as a function of their concentration φ and their preparation state. Simple scaling ideas reproduce the prediction of James and Guth for the modulus of networks swollen in a θ solvent (G ∼ φ1/3) but lead to a new prediction in a good solvent (G ∼ φ7/12). We also suggest that both fully swollen modulus and dry modulus are related to swelling in ways that are independent of the network preparation details. By cross-linking long chains at low concentration and removing the solvent, many temporary entanglements are formed that force each network strand into a double-folded treelike compact configuration. These deswollen networks are capable of stretching by enormous amounts (∼100X) without breaking (superelastic) and have a much lower modulus than melt-cross-linked networks. The energy stored in temporary entanglements during deswelling is released upon stretching, leading to a weaker-than-linear dependence of stress σ on elongation λ in tension (σ ∼ λ1/3). © 1994 American Chemical Society

Full Text

Duke Authors

Cited Authors

  • Obukhov, SP; Rubinstein, M; Colby, RH

Published Date

  • 1994

Published In

International Standard Serial Number (ISSN)

  • 1520-5835

Digital Object Identifier (DOI)

  • 10.1021/ma00090a012