High-Performance Alkaline Organic Redox Flow Batteries Based on 2-Hydroxy-3-carboxy-1,4-naphthoquinone

Journal Article (Journal Article)

Aqueous redox flow batteries (ARFBs) based on the electrolyte solutions of redox-active organic molecules are very attractive for the application of large-scale electrochemical energy storage. We propose a high-performance ARFB system utilizing 2-hydroxy-3-carboxy-1,4-naphthoquinone (2,3-HCNQ) and K4Fe(CN)6 as the anolyte and catholyte active species, respectively. The 2,3-HCNQ molecule exhibits high solubility and can carry out a reversible two-electron redox process with rapid redox kinetics. The assembled 2,3-HCNQ/K4Fe(CN)6 ARFB delivered a cell voltage of 1.02 V and realized a peak power density of 0.255 W cm-2. The 2,3-HCNQ/K4Fe(CN)6 ARFB can be stably operated at a current density of 100 mA cm-2 for long-term cycling (with a capacity retention of ∼94.7% after 100 cycles).

Full Text

Duke Authors

Cited Authors

  • Wang, C; Yang, Z; Wang, Y; Zhao, P; Yan, W; Zhu, G; Ma, L; Yu, B; Wang, L; Li, G; Liu, J; Jin, Z

Published Date

  • October 12, 2018

Published In

Volume / Issue

  • 3 / 10

Start / End Page

  • 2404 - 2409

Electronic International Standard Serial Number (EISSN)

  • 2380-8195

Digital Object Identifier (DOI)

  • 10.1021/acsenergylett.8b01296

Citation Source

  • Scopus