Stereochemically active lead chloride enantiomers mediated by homochiral organic cation

Published

Journal Article

© 2018 Elsevier Ltd Two-dimensional ((S)-1-(1-naphthyl)ethylamineH) 2 Pb 4 Cl 10 ·2DMF (1) and ((R)-1-(1-naphthyl)ethylamineH) 2 Pb 4 Cl 10 ·2DMF (2) have been synthesized using the corresponding homochiral organic cations. The lead atoms within the structure adopt a variety of coordination geometries, with Pb(II)Cl 6 adopting a distorted pentagonal pyramid geometry and exhibiting stereochemically active lone-pair electrons, instead of a more typical octahedral geometry with less stereochemical activity.

Full Text

Duke Authors

Cited Authors

  • Zhu, LL; Huang, YE; Lin, YP; Huang, XY; Liu, HQ; Mitzi, DB; Du, KZ

Published Date

  • January 15, 2019

Published In

Start / End Page

  • 445 - 448

International Standard Serial Number (ISSN)

  • 0277-5387

Digital Object Identifier (DOI)

  • 10.1016/j.poly.2018.11.026

Citation Source

  • Scopus