Ring-Closing Metathesis and Ring-Opening Metathesis Polymerization toward Main-Chain Ferrocene-Containing Polymers
Publication
, Journal Article
Sha, Y; Zhang, Y; Zhu, T; Tan, S; Cha, Y; Craig, SL; Tang, C
Published in: Macromolecules
November 27, 2018
We report the preparation of cyclic ferrocenyl olefins with various substituents and different ring sizes by ring-closing metathesis (RCM). These ferrocene-containing monomers were subject to ring-opening metathesis polymerization (ROMP), leading to main-chain ferrocene-containing homopolymers, random copolymers, and block copolymers. Depending on the substituents, ferrocenyl homopolymers are semicrystalline or amorphous with good solubility. A semicrystalline polymer was used in the crystallization-driven self-assembly (CDSA) of block copolymers to generate platelet nanostructures.
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Published In
Macromolecules
DOI
EISSN
1520-5835
ISSN
0024-9297
Publication Date
November 27, 2018
Volume
51
Issue
22
Start / End Page
9131 / 9139
Related Subject Headings
- Polymers
- 40 Engineering
- 34 Chemical sciences
- 09 Engineering
- 03 Chemical Sciences
Citation
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MLA
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Sha, Y., Zhang, Y., Zhu, T., Tan, S., Cha, Y., Craig, S. L., & Tang, C. (2018). Ring-Closing Metathesis and Ring-Opening Metathesis Polymerization toward Main-Chain Ferrocene-Containing Polymers. Macromolecules, 51(22), 9131–9139. https://doi.org/10.1021/acs.macromol.8b02064
Sha, Y., Y. Zhang, T. Zhu, S. Tan, Y. Cha, S. L. Craig, and C. Tang. “Ring-Closing Metathesis and Ring-Opening Metathesis Polymerization toward Main-Chain Ferrocene-Containing Polymers.” Macromolecules 51, no. 22 (November 27, 2018): 9131–39. https://doi.org/10.1021/acs.macromol.8b02064.
Sha Y, Zhang Y, Zhu T, Tan S, Cha Y, Craig SL, et al. Ring-Closing Metathesis and Ring-Opening Metathesis Polymerization toward Main-Chain Ferrocene-Containing Polymers. Macromolecules. 2018 Nov 27;51(22):9131–9.
Sha, Y., et al. “Ring-Closing Metathesis and Ring-Opening Metathesis Polymerization toward Main-Chain Ferrocene-Containing Polymers.” Macromolecules, vol. 51, no. 22, Nov. 2018, pp. 9131–39. Scopus, doi:10.1021/acs.macromol.8b02064.
Sha Y, Zhang Y, Zhu T, Tan S, Cha Y, Craig SL, Tang C. Ring-Closing Metathesis and Ring-Opening Metathesis Polymerization toward Main-Chain Ferrocene-Containing Polymers. Macromolecules. 2018 Nov 27;51(22):9131–9139.
Published In
Macromolecules
DOI
EISSN
1520-5835
ISSN
0024-9297
Publication Date
November 27, 2018
Volume
51
Issue
22
Start / End Page
9131 / 9139
Related Subject Headings
- Polymers
- 40 Engineering
- 34 Chemical sciences
- 09 Engineering
- 03 Chemical Sciences