Sulfamate Esters Guide C(3)-Selective Xanthylation of Alkanes.


Journal Article

Owing to the pervasiveness of hydroxyl groups in natural isolates, alcohol derivatives are alluring directing groups. Herein, an alcohol-derived sulfamate ester guides the light-initiated xanthylation of primary, secondary, or tertiary centers. This process enables formal directed deuteration, azidation, thiolation, and vinylation reactions.

Full Text

Duke Authors

Cited Authors

  • Ayer, SK; Roizen, JL

Published Date

  • March 2019

Published In

Volume / Issue

  • 84 / 6

Start / End Page

  • 3508 - 3523

PubMed ID

  • 30779561

Pubmed Central ID

  • 30779561

Electronic International Standard Serial Number (EISSN)

  • 1520-6904

International Standard Serial Number (ISSN)

  • 0022-3263

Digital Object Identifier (DOI)

  • 10.1021/acs.joc.9b00105


  • eng