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Control of Mesh Size and Modulus by Kinetically Dependent Cross-Linking in Hydrogels.

Publication ,  Journal Article
Zander, ZK; Hua, G; Wiener, CG; Vogt, BD; Becker, ML
Published in: Advanced materials (Deerfield Beach, Fla.)
October 2015

Kinetically controlled cross-linking processes produce mechanically distinguishable hydrogels using identical precursor chemistry. The oxime ligation demonstrates tunable reaction kinetics with pH and buffer strength, which induce changes in the structural features of hydrogels and determine their mechanical properties. Small-angle neutron scattering and swelling studies provide an insight into how structural properties correlate with mechanical properties for this hydrogel system.

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Published In

Advanced materials (Deerfield Beach, Fla.)

DOI

EISSN

1521-4095

ISSN

0935-9648

Publication Date

October 2015

Volume

27

Issue

40

Start / End Page

6283 / 6288

Related Subject Headings

  • Scattering, Small Angle
  • Rheology
  • Neutron Diffraction
  • Nanoscience & Nanotechnology
  • Molecular Structure
  • Materials Testing
  • Kinetics
  • Hydrogen-Ion Concentration
  • Hydrogels
  • 51 Physical sciences
 

Citation

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Zander, Z. K., Hua, G., Wiener, C. G., Vogt, B. D., & Becker, M. L. (2015). Control of Mesh Size and Modulus by Kinetically Dependent Cross-Linking in Hydrogels. Advanced Materials (Deerfield Beach, Fla.), 27(40), 6283–6288. https://doi.org/10.1002/adma.201501822
Zander, Zachary K., Geng Hua, Clinton G. Wiener, Bryan D. Vogt, and Matthew L. Becker. “Control of Mesh Size and Modulus by Kinetically Dependent Cross-Linking in Hydrogels.Advanced Materials (Deerfield Beach, Fla.) 27, no. 40 (October 2015): 6283–88. https://doi.org/10.1002/adma.201501822.
Zander ZK, Hua G, Wiener CG, Vogt BD, Becker ML. Control of Mesh Size and Modulus by Kinetically Dependent Cross-Linking in Hydrogels. Advanced materials (Deerfield Beach, Fla). 2015 Oct;27(40):6283–8.
Zander, Zachary K., et al. “Control of Mesh Size and Modulus by Kinetically Dependent Cross-Linking in Hydrogels.Advanced Materials (Deerfield Beach, Fla.), vol. 27, no. 40, Oct. 2015, pp. 6283–88. Epmc, doi:10.1002/adma.201501822.
Zander ZK, Hua G, Wiener CG, Vogt BD, Becker ML. Control of Mesh Size and Modulus by Kinetically Dependent Cross-Linking in Hydrogels. Advanced materials (Deerfield Beach, Fla). 2015 Oct;27(40):6283–6288.
Journal cover image

Published In

Advanced materials (Deerfield Beach, Fla.)

DOI

EISSN

1521-4095

ISSN

0935-9648

Publication Date

October 2015

Volume

27

Issue

40

Start / End Page

6283 / 6288

Related Subject Headings

  • Scattering, Small Angle
  • Rheology
  • Neutron Diffraction
  • Nanoscience & Nanotechnology
  • Molecular Structure
  • Materials Testing
  • Kinetics
  • Hydrogen-Ion Concentration
  • Hydrogels
  • 51 Physical sciences