Measurement of single-wall nanotube dispersion by size exclusion chromatography

Journal Article (Journal Article)

Size exclusion chromatography (SEC) is shown to be an effective method to characterize single-wall carbon nanotube (SWNT) dispersions. SEC separates nanotube dispersions by size, and an on-line viscosity detector gives intrinsic viscosity as a function of hydrodynamic size, as is determined by universal calibration. The scaling contains information about the shape of the dispersed particles. This characterization method was tested on three representative dispersions, octadecylamine functionalization (SWNT-ODA) in tetrahydrofuran (THF), butyl group functionalization (SWNT-butyl) in THF, and DNA wrapping (SWNT/DNA) in aqueous solution. Significant differences between the dispersions were found. Small-angle neutron scattering (SANS) and atomic force microscopy (AFM) produced results consistent with the SEC method.

Full Text

Duke Authors

Cited Authors

  • Bauer, BJ; Becker, ML; Bajpai, V; Fagan, JA; Hobbie, EK; Migler, K; Guttman, CM; Blair, WR

Published Date

  • December 6, 2007

Published In

Volume / Issue

  • 111 / 48

Start / End Page

  • 17914 - 17918

Electronic International Standard Serial Number (EISSN)

  • 1932-7455

International Standard Serial Number (ISSN)

  • 1932-7447

Digital Object Identifier (DOI)

  • 10.1021/jp071494q

Citation Source

  • Scopus