Copper Catalyzed C-N Cross-Coupling Reaction of Aryl Boronic Acids at Room Temperature through Chelation Assistance.
Publication
, Journal Article
Sahoo, H; Mukherjee, S; Grandhi, GS; Selvakumar, J; Baidya, M
Published in: The Journal of organic chemistry
March 2017
A copper-catalyzed selective C-N cross-coupling has been developed based on chelation-assisted amidation of readily available aryl boronic acids at room-temperature under open-flask conditions. The reaction is scalable and tolerates a wide spectrum of functional groups delivering fully substituted unsymmetrical amides in high yields (up to 96%). The C-N cross coupling also established with aryl silanes, extending the palette of coupling partners of this strategy.
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Published In
The Journal of organic chemistry
DOI
EISSN
1520-6904
ISSN
0022-3263
Publication Date
March 2017
Volume
82
Issue
5
Start / End Page
2764 / 2771
Related Subject Headings
- Organic Chemistry
- 3405 Organic chemistry
- 3404 Medicinal and biomolecular chemistry
- 0305 Organic Chemistry
- 0304 Medicinal and Biomolecular Chemistry
Citation
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Sahoo, H., Mukherjee, S., Grandhi, G. S., Selvakumar, J., & Baidya, M. (2017). Copper Catalyzed C-N Cross-Coupling Reaction of Aryl Boronic Acids at Room Temperature through Chelation Assistance. The Journal of Organic Chemistry, 82(5), 2764–2771. https://doi.org/10.1021/acs.joc.7b00002
Sahoo, Harekrishna, Sayan Mukherjee, Gowri Sankar Grandhi, Jayaraman Selvakumar, and Mahiuddin Baidya. “Copper Catalyzed C-N Cross-Coupling Reaction of Aryl Boronic Acids at Room Temperature through Chelation Assistance.” The Journal of Organic Chemistry 82, no. 5 (March 2017): 2764–71. https://doi.org/10.1021/acs.joc.7b00002.
Sahoo H, Mukherjee S, Grandhi GS, Selvakumar J, Baidya M. Copper Catalyzed C-N Cross-Coupling Reaction of Aryl Boronic Acids at Room Temperature through Chelation Assistance. The Journal of organic chemistry. 2017 Mar;82(5):2764–71.
Sahoo, Harekrishna, et al. “Copper Catalyzed C-N Cross-Coupling Reaction of Aryl Boronic Acids at Room Temperature through Chelation Assistance.” The Journal of Organic Chemistry, vol. 82, no. 5, Mar. 2017, pp. 2764–71. Epmc, doi:10.1021/acs.joc.7b00002.
Sahoo H, Mukherjee S, Grandhi GS, Selvakumar J, Baidya M. Copper Catalyzed C-N Cross-Coupling Reaction of Aryl Boronic Acids at Room Temperature through Chelation Assistance. The Journal of organic chemistry. 2017 Mar;82(5):2764–2771.
Published In
The Journal of organic chemistry
DOI
EISSN
1520-6904
ISSN
0022-3263
Publication Date
March 2017
Volume
82
Issue
5
Start / End Page
2764 / 2771
Related Subject Headings
- Organic Chemistry
- 3405 Organic chemistry
- 3404 Medicinal and biomolecular chemistry
- 0305 Organic Chemistry
- 0304 Medicinal and Biomolecular Chemistry