Skip to main content

Photolysis of some ortho-methylated monochlorobiphenyls

Publication ,  Journal Article
Bunce, NJ; Deschutter, CT; Toone, EJ
Published in: Journal of the Chemical Society, Perkin Transactions 2
January 1, 1983

A series of monochloro-o-methylated biphenyls was photolysed. Quantum yields of dechlorination lie in between the low values observed for 3- and 4-chlorobiphenyl and the high values obtained for 2-chlorobiphenyl. The results are interpreted in terms of raising the energy of the excited state due to steric crowding of the ortho-substituent and relief of strain upon the departure of an ortho-chlorine.

Duke Scholars

Altmetric Attention Stats
Dimensions Citation Stats

Published In

Journal of the Chemical Society, Perkin Transactions 2

DOI

ISSN

1472-779X

Publication Date

January 1, 1983

Issue

6

Start / End Page

859 / 861

Related Subject Headings

  • Organic Chemistry
 

Citation

APA
Chicago
ICMJE
MLA
NLM
Bunce, N. J., Deschutter, C. T., & Toone, E. J. (1983). Photolysis of some ortho-methylated monochlorobiphenyls. Journal of the Chemical Society, Perkin Transactions 2, (6), 859–861. https://doi.org/10.1039/P29830000859
Bunce, N. J., C. T. Deschutter, and E. J. Toone. “Photolysis of some ortho-methylated monochlorobiphenyls.” Journal of the Chemical Society, Perkin Transactions 2, no. 6 (January 1, 1983): 859–61. https://doi.org/10.1039/P29830000859.
Bunce NJ, Deschutter CT, Toone EJ. Photolysis of some ortho-methylated monochlorobiphenyls. Journal of the Chemical Society, Perkin Transactions 2. 1983 Jan 1;(6):859–61.
Bunce, N. J., et al. “Photolysis of some ortho-methylated monochlorobiphenyls.” Journal of the Chemical Society, Perkin Transactions 2, no. 6, Jan. 1983, pp. 859–61. Scopus, doi:10.1039/P29830000859.
Bunce NJ, Deschutter CT, Toone EJ. Photolysis of some ortho-methylated monochlorobiphenyls. Journal of the Chemical Society, Perkin Transactions 2. 1983 Jan 1;(6):859–861.

Published In

Journal of the Chemical Society, Perkin Transactions 2

DOI

ISSN

1472-779X

Publication Date

January 1, 1983

Issue

6

Start / End Page

859 / 861

Related Subject Headings

  • Organic Chemistry