Pyruvate Aldolases as Reagents for Stereospecific Aldol Condensation
KDPG aldolase, a representative member of the largest but as of yet unexplored group of aldolases which utilize pyruvate as the nucleophilic component in aldol condensation, accepts a number of unnatural aldehydes as electrophiles in stereospecific aldol condensation, providing access to highly and differentially functionalized α-keto acid products. © 1992, American Chemical Society. All rights reserved.
Allen, ST; Heintzelman, GR; Toone, EJ
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