Palladium-catalyzed intramolecular oxidative alkylation of unactivated olefins.
Publication
, Journal Article
Pei, T; Wang, X; Widenhoefer, RA
Published in: Journal of the American Chemical Society
January 2003
Reaction of 5,5-dimethyl-8-nonene-2,4-dione catalyzed by PdCl2(CH3CN)2 (5 mol %) in the presence of CuCl2 (2.5 equiv) at room temperature for 3 h formed 2-acetyl-3,6,6-trimethyl-2-cyclohexenone in 96% isolated yield. Palladium-catalyzed intramolecular oxidative alkylation tolerated a range of substitution and was applicable to the synthesis of spirobicyclic compounds and to the cyclization of zeta-alkenyl beta-keto esters.
Duke Scholars
Published In
Journal of the American Chemical Society
DOI
EISSN
1520-5126
ISSN
0002-7863
Publication Date
January 2003
Volume
125
Issue
3
Start / End Page
648 / 649
Related Subject Headings
- General Chemistry
- 40 Engineering
- 34 Chemical sciences
- 03 Chemical Sciences
Citation
APA
Chicago
ICMJE
MLA
NLM
Pei, T., Wang, X., & Widenhoefer, R. A. (2003). Palladium-catalyzed intramolecular oxidative alkylation of unactivated olefins. Journal of the American Chemical Society, 125(3), 648–649. https://doi.org/10.1021/ja026317b
Pei, Tao, Xiang Wang, and Ross A. Widenhoefer. “Palladium-catalyzed intramolecular oxidative alkylation of unactivated olefins.” Journal of the American Chemical Society 125, no. 3 (January 2003): 648–49. https://doi.org/10.1021/ja026317b.
Pei T, Wang X, Widenhoefer RA. Palladium-catalyzed intramolecular oxidative alkylation of unactivated olefins. Journal of the American Chemical Society. 2003 Jan;125(3):648–9.
Pei, Tao, et al. “Palladium-catalyzed intramolecular oxidative alkylation of unactivated olefins.” Journal of the American Chemical Society, vol. 125, no. 3, Jan. 2003, pp. 648–49. Epmc, doi:10.1021/ja026317b.
Pei T, Wang X, Widenhoefer RA. Palladium-catalyzed intramolecular oxidative alkylation of unactivated olefins. Journal of the American Chemical Society. 2003 Jan;125(3):648–649.
Published In
Journal of the American Chemical Society
DOI
EISSN
1520-5126
ISSN
0002-7863
Publication Date
January 2003
Volume
125
Issue
3
Start / End Page
648 / 649
Related Subject Headings
- General Chemistry
- 40 Engineering
- 34 Chemical sciences
- 03 Chemical Sciences