Cyclization/hydrosilylation of functionalized diynes catalyzed by a cationic platinum phenanthroline complex.

Published

Journal Article

[figure: see text] A 1:1 mixture of the platinum phenanthroline complex (phen)PtMe2 and B(C6F5)3 catalyzed the cyclization/hydrosilylation of functionalized 1,6- and 1,7-diynes to form silylated 1,2-dialkylidenecycloalkanes in good yield and with high Z-selectivity.

Full Text

Duke Authors

Cited Authors

  • Madine, JW; Wang, X; Widenhoefer, RA

Published Date

  • February 2001

Published In

Volume / Issue

  • 3 / 3

Start / End Page

  • 385 - 388

PubMed ID

  • 11428020

Pubmed Central ID

  • 11428020

Electronic International Standard Serial Number (EISSN)

  • 1523-7052

International Standard Serial Number (ISSN)

  • 1523-7060

Digital Object Identifier (DOI)

  • 10.1021/ol006901u

Language

  • eng