Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex

Published

Journal Article

Warming a solution of {(phen)Pd[η1:η2-CH(CH2SiEt3) CH2C(CO2Me)2CH2CH= CH2]}+[BAr4]- (4) at -41 °C led to first-order decay (κ = (4.7 ± 0.3) × 10-4 M s-1, ΔG‡ = 17.1 ± 0.1 kcal mol-1) with formation of the palladium cyclopentylmethyl complex {(phen)Pd-[CH2 CHCH2CC(CO2Me)2CH2CHCH2 SiEt3](NC Ar)}+-[BAr4]- (5) in 96 ± 10% yield (1H NMR).

Full Text

Duke Authors

Cited Authors

  • Perch, NS; Widenhoefer, RA

Published Date

  • December 10, 2001

Published In

Volume / Issue

  • 20 / 25

Start / End Page

  • 5251 - 5253

International Standard Serial Number (ISSN)

  • 0276-7333

Digital Object Identifier (DOI)

  • 10.1021/om010876u

Citation Source

  • Scopus