Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex

Journal Article (Journal Article)

Warming a solution of {(phen)Pd[η :η -CH(CH SiEt ) CH C(CO Me) CH CH= CH ]} [BAr ] (4) at -41 °C led to first-order decay (κ = (4.7 ± 0.3) × 10 M s , ΔG‡ = 17.1 ± 0.1 kcal mol ) with formation of the palladium cyclopentylmethyl complex {(phen)Pd-[CH CHCH CC(CO Me) CH CHCH SiEt ](NC Ar)} -[BAr ] (5) in 96 ± 10% yield ( H NMR). 1 2 + - -4 -1 -1 + - 1 2 3 2 2 2 2 2 4 2 2 2 2 2 2 3 4

Full Text

Duke Authors

Cited Authors

  • Perch, NS; Widenhoefer, RA

Published Date

  • December 10, 2001

Published In

Volume / Issue

  • 20 / 25

Start / End Page

  • 5251 - 5253

International Standard Serial Number (ISSN)

  • 0276-7333

Digital Object Identifier (DOI)

  • 10.1021/om010876u

Citation Source

  • Scopus