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Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex

Publication ,  Journal Article
Perch, NS; Widenhoefer, RA
Published in: Organometallics
December 10, 2001

Warming a solution of {(phen)Pd[η1:η2-CH(CH2SiEt3) CH2C(CO2Me)2CH2CH= CH2]}+[BAr4]- (4) at -41 °C led to first-order decay (κ = (4.7 ± 0.3) × 10-4 M s-1, ΔG‡ = 17.1 ± 0.1 kcal mol-1) with formation of the palladium cyclopentylmethyl complex {(phen)Pd-[CH2 CHCH2CC(CO2Me)2CH2CHCH2 SiEt3](NC Ar)}+-[BAr4]- (5) in 96 ± 10% yield (1H NMR).

Duke Scholars

Published In

Organometallics

DOI

ISSN

0276-7333

Publication Date

December 10, 2001

Volume

20

Issue

25

Start / End Page

5251 / 5253

Related Subject Headings

  • Organic Chemistry
  • 3406 Physical chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0305 Organic Chemistry
  • 0302 Inorganic Chemistry
 

Citation

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Perch, N. S., & Widenhoefer, R. A. (2001). Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex. Organometallics, 20(25), 5251–5253. https://doi.org/10.1021/om010876u
Perch, N. S., and R. A. Widenhoefer. “Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex.” Organometallics 20, no. 25 (December 10, 2001): 5251–53. https://doi.org/10.1021/om010876u.
Perch, N. S., and R. A. Widenhoefer. “Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex.” Organometallics, vol. 20, no. 25, Dec. 2001, pp. 5251–53. Scopus, doi:10.1021/om010876u.
Journal cover image

Published In

Organometallics

DOI

ISSN

0276-7333

Publication Date

December 10, 2001

Volume

20

Issue

25

Start / End Page

5251 / 5253

Related Subject Headings

  • Organic Chemistry
  • 3406 Physical chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0305 Organic Chemistry
  • 0302 Inorganic Chemistry