The two-state reduction for electron and hole transfer in bridge-mediated electron-transfer reactions

Published

Journal Article

We present a unified analysis of the two-state reduction in bridge-mediated electron transfer for both electron and hole transfer. The parameter that characterizes the leading error associated with a two-state reduction is derived in the energy and time domains. A precise definition of the tunnelling energy is given. We also derive analytically the regimes of validity of the two-state reduction and we interpret it in terms of the time evolution of the purely electronic part of the electron-transfer probability. © 1993.

Full Text

Duke Authors

Cited Authors

  • Skourtis, SS; Beratan, DN; Onuchic, JN

Published Date

  • October 15, 1993

Published In

Volume / Issue

  • 176 / 2-3

Start / End Page

  • 501 - 520

International Standard Serial Number (ISSN)

  • 0301-0104

Digital Object Identifier (DOI)

  • 10.1016/0301-0104(93)80258-B

Citation Source

  • Scopus