Natural circular Dichroism of Co(H2O)62+ and Cu(H2O)62+ in a Chiral Lattice

Published

Journal Article

The circular dichroism spectra of single, enantiomorphic crystals of 3a-Zn(H2O)6SeO4 doped with cobalt(II) and copper(1I) have been measured at ambient and cryogenic temperatures in the visible and near-infrared regions. Cotton effects associated with the ligand field bands of Co(H2O)62+ and Cu(H2O)62+ are observed and, for the cobalt species, exhibit extensive structure associated with both spin-forbidden bands and vibronic effects. In both cases rotational strengths increase substantially at lower temperatures and all bands in both cases (with only one exception) have the same sign in a given enantiomorph. © 1971.

Full Text

Duke Authors

Cited Authors

  • Gailey, KD; Palmer, RA

Published Date

  • February 15, 1972

Published In

Volume / Issue

  • 13 / 2

Start / End Page

  • 176 - 180

International Standard Serial Number (ISSN)

  • 0009-2614

Digital Object Identifier (DOI)

  • 10.1016/0009-2614(72)80071-X

Citation Source

  • Scopus