Single-Crystal Electronic Absorption of Tris(1,3-diphenyl-1,3-propanedionato)aquoneodymium(III): Oscillator Strength of the 4
G5/2 Hypersensitive Transition
The ligand polarization model is examined for the calculation of f → f electronic intensity in the 4I9/2 → 4G5/2 hypersensitive transition of tris(1,3-diphenyl-1,3-propanedionato)aquoneodymium(III). The electronic oscillator strengths of the single crystal are found experimentally and used in the determination of the phenomenological parameters of the Judd-Ofelt equation. Theoretical hypersensitive intensity calculations are based on X-ray structural data and average ligand polarizabilities and are compared to experimental values. © 1981, American Chemical Society. All rights reserved.
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