Single-Crystal Electronic Absorption of Tris(1,3-diphenyl-1,3-propanedionato)aquoneodymium(III): Oscillator Strength of the 4 I9/2→4 G5/2 Hypersensitive Transition

Journal Article (Journal Article)

The ligand polarization model is examined for the calculation of f → f electronic intensity in the 4I9/2 → 4G5/2 hypersensitive transition of tris(1,3-diphenyl-1,3-propanedionato)aquoneodymium(III). The electronic oscillator strengths of the single crystal are found experimentally and used in the determination of the phenomenological parameters of the Judd-Ofelt equation. Theoretical hypersensitive intensity calculations are based on X-ray structural data and average ligand polarizabilities and are compared to experimental values. © 1981, American Chemical Society. All rights reserved.

Full Text

Duke Authors

Cited Authors

  • Kirby, AF; Palmer, RA

Published Date

  • January 1, 1981

Published In

Volume / Issue

  • 20 / 4

Start / End Page

  • 1030 - 1033

Electronic International Standard Serial Number (EISSN)

  • 1520-510X

International Standard Serial Number (ISSN)

  • 0020-1669

Digital Object Identifier (DOI)

  • 10.1021/ic50218a016

Citation Source

  • Scopus