Silane-promoted cycloisomerization of functionalized 1,6-dienes catalyzed by a cationic (π-allyl)palladium complex
Publication
, Journal Article
Widenhoefer, RA; Perch, NS
Published in: Organic Letters
October 7, 1999
(matrix presented) A 1:1 mixture of the (π-allyl)palladium complex (η3-C3H5)Pd(Cl)PCy3 and NaB[3,5-C6H3(CF3)2]4 in the presence of HSiEt3 catalyzed the cycloisomerization of functionalized 1,6-dienes to form 1,2-disubstituted cyclopentenes in good yield with high selectivity (typically >94%). The protocol tolerated a range of functional groups and substitution at one of the allylic carbon atoms.
Duke Scholars
Published In
Organic Letters
DOI
ISSN
1523-7060
Publication Date
October 7, 1999
Volume
1
Issue
7
Start / End Page
1103 / 1105
Related Subject Headings
- Organic Chemistry
- 34 Chemical sciences
- 03 Chemical Sciences
Citation
APA
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ICMJE
MLA
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Widenhoefer, R. A., & Perch, N. S. (1999). Silane-promoted cycloisomerization of functionalized 1,6-dienes catalyzed by a cationic (π-allyl)palladium complex. Organic Letters, 1(7), 1103–1105. https://doi.org/10.1021/ol9908981
Widenhoefer, R. A., and N. S. Perch. “Silane-promoted cycloisomerization of functionalized 1,6-dienes catalyzed by a cationic (π-allyl)palladium complex.” Organic Letters 1, no. 7 (October 7, 1999): 1103–5. https://doi.org/10.1021/ol9908981.
Widenhoefer RA, Perch NS. Silane-promoted cycloisomerization of functionalized 1,6-dienes catalyzed by a cationic (π-allyl)palladium complex. Organic Letters. 1999 Oct 7;1(7):1103–5.
Widenhoefer, R. A., and N. S. Perch. “Silane-promoted cycloisomerization of functionalized 1,6-dienes catalyzed by a cationic (π-allyl)palladium complex.” Organic Letters, vol. 1, no. 7, Oct. 1999, pp. 1103–05. Scopus, doi:10.1021/ol9908981.
Widenhoefer RA, Perch NS. Silane-promoted cycloisomerization of functionalized 1,6-dienes catalyzed by a cationic (π-allyl)palladium complex. Organic Letters. 1999 Oct 7;1(7):1103–1105.
Published In
Organic Letters
DOI
ISSN
1523-7060
Publication Date
October 7, 1999
Volume
1
Issue
7
Start / End Page
1103 / 1105
Related Subject Headings
- Organic Chemistry
- 34 Chemical sciences
- 03 Chemical Sciences