Palladium-catalyzed intramolecular hydrosilylation of alkenylsilanes: Selective formation of six-membered silicon heterocycles

Published

Journal Article

The cationic palladium complex (phen)Pd(Me)(OEt2)+BAr4- [phen = 1,10-phenanthroline; Ar = 3,5-C6Hs(CF3)2] catalyzed the intramolecular hydrosilylation of 4-pentenylsilanes and 5-hexenylsilanes to form silacyclohexanes in 43-87% isolated yield and with excellent regioselectivity (typically ≥ 98:1). © 1998 American Chemical Society.

Full Text

Duke Authors

Cited Authors

  • Widenhoefer, RA; Krzyzanowska, B; Webb-Wood, G

Published Date

  • January 1, 1998

Published In

Volume / Issue

  • 17 / 23

Start / End Page

  • 5124 - 5127

International Standard Serial Number (ISSN)

  • 0276-7333

Digital Object Identifier (DOI)

  • 10.1021/om980585u

Citation Source

  • Scopus