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Platinum-Catalyzed Intermolecular Hydroamination of Unactivated Olefins with Carboxamides

Publication ,  Journal Article
Wang, X; Widenhoefer, RA
Published in: Organometallics
April 12, 2004

Reaction of benzamide with a catalytic 1:2 mixture of[PtCl 2(H 2C=CH 2)] 2 (2.5 mol%) and PPh 3 in dioxane at 120°C for 24 h led to isolation of N-ethylbenzamide in 97% yield. A range of primary, acyclic aryl and alkyl carboxamides and secondary cyclic carboxamides and carbamates also underwent platinum-catalyzed addition to ethylene and propylene.

Duke Scholars

Published In

Organometallics

DOI

ISSN

0276-7333

Publication Date

April 12, 2004

Volume

23

Issue

8

Start / End Page

1649 / 1651

Related Subject Headings

  • Organic Chemistry
  • 3406 Physical chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0305 Organic Chemistry
  • 0302 Inorganic Chemistry
 

Citation

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MLA
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Wang, X., & Widenhoefer, R. A. (2004). Platinum-Catalyzed Intermolecular Hydroamination of Unactivated Olefins with Carboxamides. Organometallics, 23(8), 1649–1651. https://doi.org/10.1021/om0498549
Wang, X., and R. A. Widenhoefer. “Platinum-Catalyzed Intermolecular Hydroamination of Unactivated Olefins with Carboxamides.” Organometallics 23, no. 8 (April 12, 2004): 1649–51. https://doi.org/10.1021/om0498549.
Wang X, Widenhoefer RA. Platinum-Catalyzed Intermolecular Hydroamination of Unactivated Olefins with Carboxamides. Organometallics. 2004 Apr 12;23(8):1649–51.
Wang, X., and R. A. Widenhoefer. “Platinum-Catalyzed Intermolecular Hydroamination of Unactivated Olefins with Carboxamides.” Organometallics, vol. 23, no. 8, Apr. 2004, pp. 1649–51. Scopus, doi:10.1021/om0498549.
Wang X, Widenhoefer RA. Platinum-Catalyzed Intermolecular Hydroamination of Unactivated Olefins with Carboxamides. Organometallics. 2004 Apr 12;23(8):1649–1651.
Journal cover image

Published In

Organometallics

DOI

ISSN

0276-7333

Publication Date

April 12, 2004

Volume

23

Issue

8

Start / End Page

1649 / 1651

Related Subject Headings

  • Organic Chemistry
  • 3406 Physical chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0305 Organic Chemistry
  • 0302 Inorganic Chemistry