Carbocyclic analogs of C-nucleosides: a key intermediate via a novel and efficient CC ring scission

Published

Journal Article

Treatment of hydroxymethylene ketone 6 with trimethylene dithiotosylate according to literature conditions,3b led to the novel CC ring scission product 7 in high yield; also, the hydroxide-initiated cleavage4 of 1 gave the β-elimination product 13 which underwent a highly stereospecific addition of diazomethane to provide 15. © 1981.

Full Text

Duke Authors

Cited Authors

  • Saksena, AK; McPhail, AT; Onan, KD

Published Date

  • January 1, 1981

Published In

Volume / Issue

  • 22 / 22

Start / End Page

  • 2067 - 2070

International Standard Serial Number (ISSN)

  • 0040-4039

Digital Object Identifier (DOI)

  • 10.1016/S0040-4039(01)93278-2

Citation Source

  • Scopus