Cycloaddition of vinyl aziridines with unsaturated substrates. A novel rearrangement of an unsaturated nitro compound.
Journal Article (Journal Article)
Vinylaziridine 2 undergoes reaction with electrophilic acetylenes and olefins to produce 7-membered azepine derivatives. With β-nitro-styrene however, a novel rearrangement occurs, presumably via an ene reaction to form 10, the structure of which is definitively shown by x-ray diffraction. © 1981.
Full Text
Duke Authors
Cited Authors
- Hassner, A; D'Costa, R; McPhail, AT; Butler, W
Published Date
- January 1, 1981
Published In
Volume / Issue
- 22 / 38
Start / End Page
- 3691 - 3694
International Standard Serial Number (ISSN)
- 0040-4039
Digital Object Identifier (DOI)
- 10.1016/S0040-4039(01)81995-X
Citation Source
- Scopus