Thermal Transformation of Alkenoylated Aziridines into Ring-Fused Pyrrolidines
3-Phenyl- and 3-unsubstituted-2-alkenoyl-1-methylaziridines have been synthesized via Grignard reactions with the corresponding 2-cyanoaziridines. The 3-phenylated-2-alkenoylaziridines have been thermally transformed into ring-fused pyrrolidine compounds. The configurations and conformations of the aziridine and pyrrolidine compounds have been determined by 1H and 13C NMR spectroscopy and X-ray crystallography. © 1985, American Chemical Society. All rights reserved.
Wenkert, D; Ferguson, SB; Porter, B; Qvarnstrom, A; McPhail, AT
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