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Synthesis and characterization of a dimeric tris(arsino)gallane containing a nonplanar (Ga-As)2 ring: crystal structure of {[(Me3SiCH2)2As]3Ga}2

Publication ,  Journal Article
Wells, RL; Purdy, AP; Higa, KT; McPhail, AT; Pitt, CG
Published in: Journal of Organometallic Chemistry
May 12, 1987

The dimer {[(Me3SiCH2)2As]3Ga}2, only the second tris(arsino)gallane to be completely characterized, has been prepared by the reaction of (Me3SiCH2)2AsLi with GaCl3; X-ray crystallographic analysis shows it to be the first example of a compound containing a distinctly nonplanar four-membered ring of alternating four-coordinate Ga and As atoms. © 1987.

Duke Scholars

Published In

Journal of Organometallic Chemistry

DOI

ISSN

0022-328X

Publication Date

May 12, 1987

Volume

325

Issue

1-2

Related Subject Headings

  • Organic Chemistry
  • 3403 Macromolecular and materials chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0305 Organic Chemistry
  • 0302 Inorganic Chemistry
 

Citation

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Wells, R. L., Purdy, A. P., Higa, K. T., McPhail, A. T., & Pitt, C. G. (1987). Synthesis and characterization of a dimeric tris(arsino)gallane containing a nonplanar (Ga-As)2 ring: crystal structure of {[(Me3SiCH2)2As]3Ga}2. Journal of Organometallic Chemistry, 325(1–2). https://doi.org/10.1016/0022-328X(87)80412-6
Wells, R. L., A. P. Purdy, K. T. Higa, A. T. McPhail, and C. G. Pitt. “Synthesis and characterization of a dimeric tris(arsino)gallane containing a nonplanar (Ga-As)2 ring: crystal structure of {[(Me3SiCH2)2As]3Ga}2.” Journal of Organometallic Chemistry 325, no. 1–2 (May 12, 1987). https://doi.org/10.1016/0022-328X(87)80412-6.
Wells RL, Purdy AP, Higa KT, McPhail AT, Pitt CG. Synthesis and characterization of a dimeric tris(arsino)gallane containing a nonplanar (Ga-As)2 ring: crystal structure of {[(Me3SiCH2)2As]3Ga}2. Journal of Organometallic Chemistry. 1987 May 12;325(1–2).
Wells, R. L., et al. “Synthesis and characterization of a dimeric tris(arsino)gallane containing a nonplanar (Ga-As)2 ring: crystal structure of {[(Me3SiCH2)2As]3Ga}2.” Journal of Organometallic Chemistry, vol. 325, no. 1–2, May 1987. Scopus, doi:10.1016/0022-328X(87)80412-6.
Wells RL, Purdy AP, Higa KT, McPhail AT, Pitt CG. Synthesis and characterization of a dimeric tris(arsino)gallane containing a nonplanar (Ga-As)2 ring: crystal structure of {[(Me3SiCH2)2As]3Ga}2. Journal of Organometallic Chemistry. 1987 May 12;325(1–2).
Journal cover image

Published In

Journal of Organometallic Chemistry

DOI

ISSN

0022-328X

Publication Date

May 12, 1987

Volume

325

Issue

1-2

Related Subject Headings

  • Organic Chemistry
  • 3403 Macromolecular and materials chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0305 Organic Chemistry
  • 0302 Inorganic Chemistry