Highly stereoselective radical addition to a trisubstituted alkene by low temperature photolysis of thiohydroxamic esters
Published
Journal Article
Low temperature carbon radical addition to α,β-unsaturated amides of trans-2,5-dimethylpyrrolidine was achieved in high yield with high diastereoselectivity by photolysis of Barton esters. Use of an olefin substituted with three electron withdrawing groups provides synthetic versatility and regiospecificity. © 1990.
Full Text
Duke Authors
Cited Authors
- Scott, DM; McPhail, AT; Porter, NA
Published Date
- January 1, 1990
Published In
Volume / Issue
- 31 / 12
Start / End Page
- 1679 - 1682
International Standard Serial Number (ISSN)
- 0040-4039
Digital Object Identifier (DOI)
- 10.1016/S0040-4039(00)88852-8
Citation Source
- Scopus