Competition rate constants for addition of cyclohexyl radical to amide substituted alkenes: origins of acyclic stereoselection in radical additions

Journal Article (Journal Article)

Competition rate constants were determined for the addition of cyclohexyl radical to α,β unsaturated amides derived from pyrrolidine and trans-2,5-dimethylpyrrolidine. The relative rates can be understood by single crystal X-Ray analyses of the alkenes and an examination of the presumed transition state. © 1991.

Full Text

Duke Authors

Cited Authors

  • Porter, NA; Wu, WX; McPhail, AT

Published Date

  • February 4, 1991

Published In

Volume / Issue

  • 32 / 6

Start / End Page

  • 707 - 710

International Standard Serial Number (ISSN)

  • 0040-4039

Digital Object Identifier (DOI)

  • 10.1016/S0040-4039(00)74863-5

Citation Source

  • Scopus