Competition rate constants for addition of cyclohexyl radical to amide substituted alkenes: origins of acyclic stereoselection in radical additions
Journal Article (Journal Article)
Competition rate constants were determined for the addition of cyclohexyl radical to α,β unsaturated amides derived from pyrrolidine and trans-2,5-dimethylpyrrolidine. The relative rates can be understood by single crystal X-Ray analyses of the alkenes and an examination of the presumed transition state. © 1991.
Full Text
Duke Authors
Cited Authors
- Porter, NA; Wu, WX; McPhail, AT
Published Date
- February 4, 1991
Published In
Volume / Issue
- 32 / 6
Start / End Page
- 707 - 710
International Standard Serial Number (ISSN)
- 0040-4039
Digital Object Identifier (DOI)
- 10.1016/S0040-4039(00)74863-5
Citation Source
- Scopus