Competition rate constants for addition of cyclohexyl radical to amide substituted alkenes: origins of acyclic stereoselection in radical additions


Journal Article

Competition rate constants were determined for the addition of cyclohexyl radical to α,β unsaturated amides derived from pyrrolidine and trans-2,5-dimethylpyrrolidine. The relative rates can be understood by single crystal X-Ray analyses of the alkenes and an examination of the presumed transition state. © 1991.

Full Text

Duke Authors

Cited Authors

  • Porter, NA; Wu, WX; McPhail, AT

Published Date

  • February 4, 1991

Published In

Volume / Issue

  • 32 / 6

Start / End Page

  • 707 - 710

International Standard Serial Number (ISSN)

  • 0040-4039

Digital Object Identifier (DOI)

  • 10.1016/S0040-4039(00)74863-5

Citation Source

  • Scopus