Synthesis and absolute configuration of hydroxythreonine, a biosynthetic precursor of rhizobitoxine in pseudomonas
The synthesis of hydroxythreonine via osmylation of vinyl glycine has permitted a crystalline derivative to be prepared as well as comparison with naturally-derived material, allowing the assignment of the absolute configuration of the natural product as (2S, 3R). © 1993.
Pirrung, MC; Nunn, DS; McPhail, AT; Mitchell, RE
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