1,3 acyclic control in free radical reactions: Threo-selective additions

Journal Article (Journal Article)

Oxazolidinone acrylamides undergo addition reactions with alkyl iodides and allyltributylstannane to give 1,3-substituted products with a threo preference in excess of 10:1. This threo preference is highest for reactions carried out in nonpolar solvents, a result consistent with dipolar stabilization of the transition state leading to the threo product. © 1995.

Full Text

Duke Authors

Cited Authors

  • Radinov, R; Mero, CL; McPhail, AT; Porter, NA

Published Date

  • November 6, 1995

Published In

Volume / Issue

  • 36 / 45

Start / End Page

  • 8183 - 8186

International Standard Serial Number (ISSN)

  • 0040-4039

Digital Object Identifier (DOI)

  • 10.1016/0040-4039(95)01767-C

Citation Source

  • Scopus