1,3 acyclic control in free radical reactions: Threo-selective additions
Oxazolidinone acrylamides undergo addition reactions with alkyl iodides and allyltributylstannane to give 1,3-substituted products with a threo preference in excess of 10:1. This threo preference is highest for reactions carried out in nonpolar solvents, a result consistent with dipolar stabilization of the transition state leading to the threo product. © 1995.
Radinov, R; Mero, CL; McPhail, AT; Porter, NA
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