1,3 acyclic control in free radical reactions: Threo-selective additions
Journal Article (Journal Article)
Oxazolidinone acrylamides undergo addition reactions with alkyl iodides and allyltributylstannane to give 1,3-substituted products with a threo preference in excess of 10:1. This threo preference is highest for reactions carried out in nonpolar solvents, a result consistent with dipolar stabilization of the transition state leading to the threo product. © 1995.
Full Text
Duke Authors
Cited Authors
- Radinov, R; Mero, CL; McPhail, AT; Porter, NA
Published Date
- November 6, 1995
Published In
Volume / Issue
- 36 / 45
Start / End Page
- 8183 - 8186
International Standard Serial Number (ISSN)
- 0040-4039
Digital Object Identifier (DOI)
- 10.1016/0040-4039(95)01767-C
Citation Source
- Scopus