Application of ruthenium-induced macrocyclization for the construction of macrocyclic depsipeptides.
Journal Article (Journal Article)
The synthesis of a biaryl ether containing macrocyclic depsipeptide 1 was achieved in 6% overall yield. The desired macrocycle was constructed by cyclization of a phenol into eta(6)-ruthenium complex. The ruthenium metal was subsequently photolytically deprotected to obtain the macrocycle 1.
Full Text
Duke Authors
Cited Authors
- Venkatraman, S; Njoroge, FG; Girijavallabhan, V; McPhail, AT
Published Date
- May 2002
Published In
Volume / Issue
- 67 / 9
Start / End Page
- 3152 - 3155
PubMed ID
- 11975586
Electronic International Standard Serial Number (EISSN)
- 1520-6904
International Standard Serial Number (ISSN)
- 0022-3263
Digital Object Identifier (DOI)
- 10.1021/jo011106v
Language
- eng