Solution-phase synthesis of single-crystalline iron phosphide nanorods/nanowires.

Journal Article (Journal Article)

A solution-phase route for the preparation of single-crystalline iron phosphide nanorods and nanowires is reported. We have shown that the mixture of trioctylphosphine oxide (TOPO) and trioctylphosphine (TOP), which are commonly used as the solvents for semiconductor nanocrystal synthesis, is not entirely inert. In the current process, TOP, serving as phosphor source, reacts with Fe precursors to form FeP nanostructures with large aspect ratios. In addition, the experimental results show that both TOP and TOPO are necessary for the formation of FeP nanowires and their ratio appears to control the morphology of the produced FeP structures. A possible growth mechanism is discussed.

Full Text

Duke Authors

Cited Authors

  • Qian, C; Kim, F; Ma, L; Tsui, F; Yang, P; Liu, J

Published Date

  • February 2004

Published In

Volume / Issue

  • 126 / 4

Start / End Page

  • 1195 - 1198

PubMed ID

  • 14746490

Pubmed Central ID

  • 14746490

Electronic International Standard Serial Number (EISSN)

  • 1520-5126

International Standard Serial Number (ISSN)

  • 0002-7863

Digital Object Identifier (DOI)

  • 10.1021/ja038401c


  • eng