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Molecular Bridge Effects on Distant Charge Tunneling

Publication ,  Journal Article
Onuchic, JN; Beratan, DN
Published in: Journal of the American Chemical Society
October 1, 1987

The question arises as to whether different hydrocarbon bridges should give different electron-transfer rates. We answer this question on the basis of energetic and topological (interference) effects that can be gleaned from one-electron models. A discussion of model compound electron-transfer rates based on this interpretation is given. The approximations implicit in the periodic models used here (and in previous work) are carefully justified. © 1987, American Chemical Society. All rights reserved.

Duke Scholars

Published In

Journal of the American Chemical Society

DOI

EISSN

1520-5126

ISSN

0002-7863

Publication Date

October 1, 1987

Volume

109

Issue

22

Start / End Page

6771 / 6778

Related Subject Headings

  • General Chemistry
  • 40 Engineering
  • 34 Chemical sciences
  • 03 Chemical Sciences
 

Citation

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ICMJE
MLA
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Onuchic, J. N., & Beratan, D. N. (1987). Molecular Bridge Effects on Distant Charge Tunneling. Journal of the American Chemical Society, 109(22), 6771–6778. https://doi.org/10.1021/ja00256a035
Onuchic, J. N., and D. N. Beratan. “Molecular Bridge Effects on Distant Charge Tunneling.” Journal of the American Chemical Society 109, no. 22 (October 1, 1987): 6771–78. https://doi.org/10.1021/ja00256a035.
Onuchic JN, Beratan DN. Molecular Bridge Effects on Distant Charge Tunneling. Journal of the American Chemical Society. 1987 Oct 1;109(22):6771–8.
Onuchic, J. N., and D. N. Beratan. “Molecular Bridge Effects on Distant Charge Tunneling.” Journal of the American Chemical Society, vol. 109, no. 22, Oct. 1987, pp. 6771–78. Scopus, doi:10.1021/ja00256a035.
Onuchic JN, Beratan DN. Molecular Bridge Effects on Distant Charge Tunneling. Journal of the American Chemical Society. 1987 Oct 1;109(22):6771–6778.
Journal cover image

Published In

Journal of the American Chemical Society

DOI

EISSN

1520-5126

ISSN

0002-7863

Publication Date

October 1, 1987

Volume

109

Issue

22

Start / End Page

6771 / 6778

Related Subject Headings

  • General Chemistry
  • 40 Engineering
  • 34 Chemical sciences
  • 03 Chemical Sciences