Limiting forms of the tunneling matrix element in the long distance bridge mediated electron transfer problem
A simple model is presented for long distance electron transfer through a bridging medium. Assumptions about the bridge mediated interaction, inherent in many other models, are shown to be limits of the more general problem. The relative importance of through bond and through space coupling is discussed. © 1985 American Institute of Physics.
Beratan, DN; Onuchic, JN; Hopfield, JJ
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