Intermolecular effect in molecular electronics.
Journal Article (Journal Article)
We investigate the effects of lateral interactions on the conductance of two molecules connected in parallel to semi-infinite leads. The method we use combines a Green function approach to quantum transport with density functional theory for the electronic properties. The system, modeled after a self-assembled monolayer, consists of benzylmercaptane molecules sandwiched between gold electrodes. We find that the conductance increases when intermolecular interaction comes into play. The source of this increase is the indirect interaction through the gold substrate rather than direct molecule-molecule interaction. A striking resonance is produced only 0.3 eV above the Fermi energy.
Full Text
Duke Authors
Cited Authors
- Liu, R; Ke, S-H; Baranger, HU; Yang, W
Published Date
- January 2005
Published In
Volume / Issue
- 122 / 4
Start / End Page
- 44703 -
PubMed ID
- 15740279
Electronic International Standard Serial Number (EISSN)
- 1089-7690
International Standard Serial Number (ISSN)
- 0021-9606
Digital Object Identifier (DOI)
- 10.1063/1.1825377
Language
- eng