Kinetics and mechanism of axial ligand substitution of alkyl cobaloximes by substituted pyridines in different solvents
Publication
, Journal Article
Heymann, JJ; Crumbliss, AL
Published in: Chemtracts
October 1, 2004
These researchers demonstrated that the trans-alkyl group in the vitamin B 12 model RCo(dmgH) 2(solvent) affects the rate and nature of the ligand exchange reaction, based on the ability of the alkyl ligand to donate electron density to the Co(III) center. The ability of the entering ligand to rapidly form a precursor encounter complex through π-π interactions affects the overall mechanism, changing from a dissociative interchange to a purely dissociative mechanism with changing π-donor capabilities of the entering ligand. © 2004 Data Trace Publishing Company.
Duke Scholars
Published In
Chemtracts
ISSN
1431-9268
Publication Date
October 1, 2004
Volume
17
Issue
10
Start / End Page
527 / 533
Related Subject Headings
- Organic Chemistry
Citation
APA
Chicago
ICMJE
MLA
NLM
Heymann, J. J., & Crumbliss, A. L. (2004). Kinetics and mechanism of axial ligand substitution of alkyl cobaloximes by substituted pyridines in different solvents. Chemtracts, 17(10), 527–533.
Heymann, J. J., and A. L. Crumbliss. “Kinetics and mechanism of axial ligand substitution of alkyl cobaloximes by substituted pyridines in different solvents.” Chemtracts 17, no. 10 (October 1, 2004): 527–33.
Heymann JJ, Crumbliss AL. Kinetics and mechanism of axial ligand substitution of alkyl cobaloximes by substituted pyridines in different solvents. Chemtracts. 2004 Oct 1;17(10):527–33.
Heymann, J. J., and A. L. Crumbliss. “Kinetics and mechanism of axial ligand substitution of alkyl cobaloximes by substituted pyridines in different solvents.” Chemtracts, vol. 17, no. 10, Oct. 2004, pp. 527–33.
Heymann JJ, Crumbliss AL. Kinetics and mechanism of axial ligand substitution of alkyl cobaloximes by substituted pyridines in different solvents. Chemtracts. 2004 Oct 1;17(10):527–533.
Published In
Chemtracts
ISSN
1431-9268
Publication Date
October 1, 2004
Volume
17
Issue
10
Start / End Page
527 / 533
Related Subject Headings
- Organic Chemistry