Chiral 2,2'-bipyridine-type N-monoxides as organocatalysts in the enantioselective allylation of aldehydes with allyltrichlorosilane.


Journal Article

[reaction: see text] The Sakurai-Hosomi-type allylation of aromatic and heteroaromatic aldehydes can be catalyzed by the new heterobidenate bipyridine monoxide PINDOX with high enantioselectivities. The sterochemical outcome is mainly controlled by the axial chirality in PINDOX, which in turn is determined by the annulated terpene units.

Full Text

Cited Authors

  • Malkov, AV; Orsini, M; Pernazza, D; Muir, KW; Langer, V; Meghani, P; Kocovský, P

Published Date

  • March 2002

Published In

Volume / Issue

  • 4 / 6

Start / End Page

  • 1047 - 1049

PubMed ID

  • 11893218

Pubmed Central ID

  • 11893218

Electronic International Standard Serial Number (EISSN)

  • 1523-7052

International Standard Serial Number (ISSN)

  • 1523-7060

Digital Object Identifier (DOI)

  • 10.1021/ol025654m


  • eng