Quadrupole spectrum of BiCl3

Journal Article (Journal Article)

Pure nuclear quadrupole resonance absorptions were observed for Bi209, Cl35, and Cl37 nuclei in polycrystalline BiCl3 at both room and liquid air temperatures. Line assignments and the evaluation of the electric field gradient asymmetry parameter allow the following coupling constants to be calculated: |eQq|Bi=318.76 Mc/sec for =0.555; |eQq|Cl35=30.196 Mc/sec, 38.310 Mc/sec. Two "forbidden" | m|=2 transitions were observed. A brief discussion of the data in connection with chemical bonding in the solid is given. © 1955 The American Physical Society.

Full Text

Duke Authors

Cited Authors

  • Robinson, HG

Published Date

  • December 1, 1955

Published In

Volume / Issue

  • 100 / 6

Start / End Page

  • 1731 - 1734

International Standard Serial Number (ISSN)

  • 0031-899X

Digital Object Identifier (DOI)

  • 10.1103/PhysRev.100.1731

Citation Source

  • Scopus