Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines.

Journal Article (Journal Article)

A 1:1 mixture of (dppf)PtCl(2) and AgOTf (5 mol%) catalyzed the intermolecular hydroamination of monosubstituted allenes with secondary alkylamines at 80 degrees C to form allylic amines in good yield with selective formation of the E-diastereomer.

Full Text

Duke Authors

Widenhoefer, Ross A.

Cited Authors

Toups, KL; Widenhoefer, RA

Published Date

March 2010

Published In

Chemical Communications

Volume / Issue

46 / 10

Start / End Page

1712 - 1714

PubMed ID

20177625

Pubmed Central ID

20177625

Electronic International Standard Serial Number (EISSN)

1364-548X

International Standard Serial Number (ISSN)

1359-7345

Digital Object Identifier (DOI)

10.1039/b925859k

Language

eng