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Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines.

Publication ,  Journal Article
Toups, KL; Widenhoefer, RA
Published in: Chemical communications (Cambridge, England)
March 2010

A 1:1 mixture of (dppf)PtCl(2) and AgOTf (5 mol%) catalyzed the intermolecular hydroamination of monosubstituted allenes with secondary alkylamines at 80 degrees C to form allylic amines in good yield with selective formation of the E-diastereomer.

Duke Scholars

Published In

Chemical communications (Cambridge, England)

DOI

EISSN

1364-548X

ISSN

1359-7345

Publication Date

March 2010

Volume

46

Issue

10

Start / End Page

1712 / 1714

Related Subject Headings

  • Stereoisomerism
  • Platinum
  • Organic Chemistry
  • Catalysis
  • Amines
  • Amination
  • Alkadienes
  • 40 Engineering
  • 34 Chemical sciences
  • 03 Chemical Sciences
 

Citation

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Toups, K. L., & Widenhoefer, R. A. (2010). Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines. Chemical Communications (Cambridge, England), 46(10), 1712–1714. https://doi.org/10.1039/b925859k
Toups, Kristina L., and Ross A. Widenhoefer. “Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines.Chemical Communications (Cambridge, England) 46, no. 10 (March 2010): 1712–14. https://doi.org/10.1039/b925859k.
Toups KL, Widenhoefer RA. Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines. Chemical communications (Cambridge, England). 2010 Mar;46(10):1712–4.
Toups, Kristina L., and Ross A. Widenhoefer. “Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines.Chemical Communications (Cambridge, England), vol. 46, no. 10, Mar. 2010, pp. 1712–14. Epmc, doi:10.1039/b925859k.
Toups KL, Widenhoefer RA. Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines. Chemical communications (Cambridge, England). 2010 Mar;46(10):1712–1714.
Journal cover image

Published In

Chemical communications (Cambridge, England)

DOI

EISSN

1364-548X

ISSN

1359-7345

Publication Date

March 2010

Volume

46

Issue

10

Start / End Page

1712 / 1714

Related Subject Headings

  • Stereoisomerism
  • Platinum
  • Organic Chemistry
  • Catalysis
  • Amines
  • Amination
  • Alkadienes
  • 40 Engineering
  • 34 Chemical sciences
  • 03 Chemical Sciences