Syntheses, X-ray crystal structures, and solution behavior of monomeric, cationic, two-coordinate gold(I) pi-alkene complexes.

Journal Article

Treatment of a suspension of (IPr)AuCl [IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidine] and AgSbF(6) (1:1) with isobutylene at room temperature for 12 h led to isolation of [(NHC)Au(eta(2)-H(2)C=CMe(2))](+) SbF(6)(-) (1a) in 98% yield, which was characterized by spectroscopy and X-ray crystallography. A number of cationic gold pi-alkene complexes were isolated employing a procedure similar to that used to isolate 1a, two of which were analyzed by X-ray crystallography. Spectroscopy, X-ray crystallography, and alkene binding studies were in accord with a gold-(pi-alkene) interaction dominated by sigma-donation from the alkene to gold.

Full Text

Duke Authors

Cited Authors

  • Brown, TJ; Dickens, MG; Widenhoefer, RA

Published Date

  • May 13, 2009

Published In

Volume / Issue

  • 131 / 18

Start / End Page

  • 6350 - 6351

PubMed ID

  • 19368391

Electronic International Standard Serial Number (EISSN)

  • 1520-5126

Digital Object Identifier (DOI)

  • 10.1021/ja9015827

Language

  • eng

Conference Location

  • United States