Computer simulations of multiple-quantum NMR experiments. I. Nonselective excitation
Journal Article (Journal Article)
The multiple-quantum (MQ evolution of anisotropic spin systems with four to eight coupled protons is analyzed using a computer for the basic three-pulse sequence. MQ intensities are first investigated as a function of preparation time. The concept of time-independent intensities is then introduced, and an algorithm for efficient computation of these quantities is described. A correlation between the distribution of dipolar coupling values and the intensity of high-quantum lines is discussed; in many cases, these intensities are predicted to be considerably larger than a simple statistical argument would suggest. The effect of varying the preparation and detection times independently is analyzed as a random walk problem. © 1984.
Full Text
Duke Authors
Cited Authors
- Murdoch, JB; Warren, WS; Weitekamp, DP; Pines, A
Published Date
- January 1, 1984
Published In
Volume / Issue
- 60 / 2
Start / End Page
- 205 - 235
International Standard Serial Number (ISSN)
- 0022-2364
Digital Object Identifier (DOI)
- 10.1016/0022-2364(84)90327-5
Citation Source
- Scopus