Analogy of Multiple-Quantum NMR to Isotopic Spin Labeling
Journal Article
The NMR of oriented molecules gives detailed structural information, but isotopic substitution is often required for analysis. An alternative to synthesizing labeled molecules is to observe multiple-quantum spectra. Symmetry arguments show that multiple-quantum transitions yield similar information and that the spectra can be predicted by analogy with labeling experiments. Several examples are shown to illustrate the versatility of this technique for determining molecular conformations and rates of intramolecular processes. © 1981, American Chemical Society. All rights reserved.
Full Text
Duke Authors
Cited Authors
- Warren, WS; Pines, A
Published Date
- January 1, 1981
Published In
Volume / Issue
- 103 / 7
Start / End Page
- 1613 - 1617
Electronic International Standard Serial Number (EISSN)
- 1520-5126
International Standard Serial Number (ISSN)
- 0002-7863
Digital Object Identifier (DOI)
- 10.1021/ja00397a001
Citation Source
- Scopus